吉林大学学报(地球科学版) ›› 2018, Vol. 48 ›› Issue (4): 1043-1049.doi: 10.13278/j.cnki.jjuese.20170100
日比娅, 孙友宏, 韩婧, 郭明义
Abakar Rabiea, Sun Youhong, Han Jing, Guo Mingyi
摘要: 为了发展油页岩催化热解方法,本文对油页岩中干酪根在催化剂(SnCl2,MoCl5,ZnCl2)作用下的热解转化进行了研究。运用傅里叶变换红外光谱(FT-IR)、X射线衍射(XRD)、热重(TG)分析等手段对样品在较低温度下(350℃)热解前后的半焦产物进行了分析,利用Coats-Redfern方法计算了热解后的残余半焦动力学参数。结果表明,催化剂可以使干酪根在350℃发生热解反应,同时也能够降低残余半焦的活化能,其中SnCl2、MoCl5和ZnCl2催化处理后残余半焦的活化能分别降低15.10、10.66和20.58 kJ/mol。
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