吉林大学学报(工学版) ›› 2018, Vol. 48 ›› Issue (4): 1045-1054.doi: 10.13229/j.cnki.jdxbgxb20170802

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Micro-morphology and gray entropy analysis of asphalt characteristics functional groups and rheological parameters under freeze-thaw cycles

NIAN Teng-fei, LI Ping, LIN Mei   

  1. School of Civil Engineering, Lanzhou University of Technology, Lanzhou 730050, China
  • Received:2017-08-01 Online:2018-07-01 Published:2018-07-01

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Abstract: In order to better link the chemical analysis with the pavement performance of asphalt binders, improve the durability of asphalt pavement in cold areas, Fourier Transform Infrared Spectroscopy (FTIR) and Dynamic Shear Rheological (DSR) test were used to analyze the changes of asphalt rheological parameters and characteristic functional groups under freeze-thaw cycles. The relationship between the rheological properties and the content of characteristic functional groups of asphalt was discussed based on gray relational entropy analysis model. The microstructure of the asphalt before and after the freeze-thaw cycle was characterized by Scanning Electron Microscopy (SEM). Results show that water-temperature aging reaction occurs in the asphalt during the freeze-thaw cycles. Under different freeze-thaw cycles, the sulfoxide and carbonyl groups in the asphalt FTIR spectrum show a significant increase. The logarithm of asphalt complex modulus has a negative growth relationship with the increase in temperature. The phase angle changes linearly with the temperature. The rutting factor exhibits and exponential decay pattern with temperature. The asphalt chemical compositions influence the rheological properties in the order carbonyl,asymmetric aliphatic,sulfoxide. The asphalt film structure appears obvious folds and flocculent areas after water freeze-thaw cycles.

Key words: road engineering, freeze-thaw cycles, asphalt, characteristic functional group, rheological parameters, gray entropy analysis, micro-morphology

CLC Number: 

  • U414.1
[1] 刘能源,颜可珍,胡迎斌,等. 基于横观各向同性的沥青路面加铺层力学分析[J]. 湖南大学学报:自然科学版,2017,44(5):96-103.
Liu Neng-yuan, Yan Ke-zhen, Hu Ying-bin,et al.Mechanical analysis of asphalt concrete overlay over old asphalt pavements considering cross-anisotropy properties[J]. Journal of Hunan University (Natural Sciences),2017,44(5):96-103.
[2] 裴建中,贾彦顺,张久鹏,等. 沥青路面结构可靠度的研究进展及展望[J]. 中国公路学报,2016,29(1):1-15.
Pei Jian-zhong, Jia Yan-shun, Zhang Jiu-peng, et al.Research progress and future development for reliability of asphalt pavement structure[J]. China Journal of Highway and Transport,2016,29(1):1-15.
[3] Mousavi M, Pahlavan F, Oldham D, et al.Multiscale investigation of oxidative aging in biomodified asphalt binder[J]. The Journal of Physical Chemistry C, 2016, 120(31):17224-17233.
[4] Ruan Y, Davison R R, Glover C J.Oxidation and viscosity hardening of polymer-modified asphalts[J]. Energy & Fuels,2003,17(4):991-998.
[5] 崔亚楠,邢永明,王岚,等. 复合胶粉改性沥青的微观结构与流变特性[J]. 高分子材料科学与工程, 2012, 28(2):41-44.
Cui Ya-nan, Xing Yong-ming, Wang Lan, et al.Micro-structure and rheological behavior of composite crumb rubber modified asphalt[J]. Polymer Materials Science & Engineering,2012, 28(2):41-44.
[6] Mallick R B, Brown E R.An evaluation of superpave binder aging methods[J]. International Journal of Pavement Engineering, 2014, 5(1):9-18.
[7] Yut I, Zofka A.Correlation between rheology and chemical composition of aged polymer-modified asphalts[J]. Construction & Building Materials,2014, 62:109-17.
[8] 侯伟. 基于灰熵法的沥青混合料低温抗裂性能影响因素研究[J]. 重庆交通大学学报:自然科学版, 2010, 29(6):904-906,1001.
Hou Wei.Research on influencing factors of low-temperature crack resistance of asphalt mixture based on grey correlation entropy method[J]. Journal of Chongqing Jiaotong University (Natural Science), 2010, 29(6): 904-906,1001.
[9] 蒋建国,张学磊,刘小明,等. 导电沥青混凝土路用性能影响因素的灰关联分析[J]. 铁道科学与工程学报,2015,12(4):784-789.
Jiang Jian-guo, Zhang Xue-lei, Liu Xiao-ming, et al.Grey relational analysis of influencing factors on pavement performance of conductive asphalt concrete[J]. Journal of Railway Science and Engineering,2015, 12(4):784-789.
[10] 应荣华,侯昭光,庞海峰. 细集料粒径对沥青砂浆黏弹性参数影响程度的灰熵分析[J]. 重庆交通大学学报:自然科学版, 2010, 29(3):398-402.
Ying Rong-hua, Hou Zhao-guang, Pang Hai-feng.Influence of fine aggregate particle size on viscoelastic parameters of asphalt mortar by gray entropy method[J]. Journal of Chongqing Jiaotong University (Natural Science), 2010, 29(3): 398-402.
[11] 张久鹏,黄晓明,马涛. 沥青混合料高温稳定性影响因素的灰关联熵分析[J]. 交通运输工程与信息学报,2008, 6(2):51-55.
Zhang Jiu-peng, Huang Xiao-ming, Ma Tao.Effect factor analysis of asphalt mixture rut-resistance property with grey relation entropy method[J]. Journal of Transportation Engineering and Information,2008, 6(2):51-55.
[12] 李秀君,张永平,许光孝,等. 基于灰熵关联法的泡沫沥青二次冷再生混合料粗集料矿料间隙率影响因素分析[J]. 水资源与水工程学报,2016, 27(5):180-184.
Li Xiu-jun, Zhang Yong-ping, Xu Guang-xiao, et al.Factors of impacting gap rate of coarse aggregate of foamed asphalt secondary cold recycled mixture based on grey correlation entropy method[J]. Journal of Water Resources&Water Engineering,2016, 27(5):180-184.
[13] Abdullah M E, Zamhari K A, Buhari R, et al. Short term and long term aging effects of asphalt binder modified with montmorillonite[J]. Key Engineering Materials, 2013, 594-595:996-1002.
[14] AASHTO. Standard method of test for determining the rheological properties of asphalt binder using a dynamic shear rheometer (DSR)[S]. 2012.
[15] 丁锐,桂泰江,蒋建明,等. 应用拉普拉斯变换和留数法求解常见非稳态扩散情况下的菲克定律[J]. 数学的实践与认识, 2017, 47(1):271-279.
Ding Rui, Gui Tai-jiang, Jiang Jian-ming, et al.Solution of fick's second law in the case of common diffusion[J]. Mathematics in Practice and Theory, 2017, 47(1):271-279.
[16] 韩吉伟,崔亚楠,李震,等. 改性沥青微观结构及低温性能的研究[J]. 功能材料, 2017, 48(2):2140-2143.
Han Ji-wei, Cui Ya-nan, Li Zhen, et al.Research on microstructure and low temperature performance of modified asphalt[J]. Journal of Functional Materials, 2017, 48(2): 2140-2143.
[17] Nian T F, Li P, Mao Y, et al.Connections between chemical composition and rheology of aged base asphalt binders during repeated freeze-thaw cycles[J]. Construction and Building Materials, 2018, 159: 338-350.
[18] Mikhailenko P, Bertron A, Ringot E.Methods for analyzing the chemical mechanisms of bitumen aging and rejuvenation with FTIR spectrometry[C]∥The 8th RILEM International Symposium on Testing and Characterization of Sustainable and Innovative Bituminous Materials, Ancona, Italy,2015:1-13.
[19] Hamzah M, Yee T, Golchin B, et al.Use of imaging technique and direct tensile test to evaluate moisture damage properties of warm mix asphalt using response surface method[J]. Construction and Building Materials, 2017, 132:323-334.
[20] 陈华鑫,陈拴发,王秉纲. 基质沥青老化行为与老化机理[J]. 山东大学学报:工学版,2009,39(2):125-130.
Chen Hua-xin, Chen Shuan-fa, Wang Bing-gang.The aging behavior and mechanism of base asphalts[J]. Journal of Shandong University (Engineering Science),2009,39(2):125-130.
[21] 崔亚楠,韩吉伟,冯蕾,等. 盐冻循环条件下改性沥青微细观结构[J]. 吉林大学学报:工学版, 2017, 47(2):452-458.
Cui Ya-nan, Han Ji-wei, Feng Lei, et al.Microstructure of asphalt under salt freezing cycles[J]. Journal of Jilin University (Engineering and Technology Edition), 2017, 47(2): 452-458.
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