吉林大学学报(工学版) ›› 2018, Vol. 48 ›› Issue (1): 212-220.doi: 10.13229/j.cnki.jdxbgxb20161298
赵宇光1, 2, 杨雪慧1, 2, 徐晓峰1, 2, 张阳阳1, 2, 宁玉恒1, 2, 3
ZHAO Yu-guang1, 2, YANG Xue-hui1, 2, XU Xiao-feng1, 2, ZHANG Yang-yang1, 2, NING Yu-heng1, 2, 3
摘要: 制备了不同处理状态(常规铸态、快速凝固态、轧制变形态)的Al-10Sr中间合金作为变质剂,其中加入Sr的质量分数为0.02%。研究了不同尺寸的Al4Sr相、变质温度及变质时间对ZL114A显微组织的影响。结果表明:常规铸态、快速凝固态的Al-10Sr变质ZL114A合金在750 ℃分别保温30 min、15 min时获得最佳变质效果,轧制态Al-10Sr变质的ZL114A合金在720 ℃时、保温15 min时共晶硅为珊瑚状,变质效果最好;Al4Sr的尺寸越小,变质效果越好,而且Al4Sr的尺寸越小,熔体温度越高,Sr变质的孕育期越短。
中图分类号:
[1] 熊艳才, 刘伯操. 铸造铝合金现状及未来发展[J]. 特种铸造及有色合金, 1998 (4): 3-7. Xiong Yan-cai, Liu Bo-cao.Review and prospect of cast aluminum alloy[J]. Specail Casting & Nonferrous Alloys, 1998(4): 3-7. [2] Hegde S, Prabhu K N.Modification of eutectic silicon in Al-Si alloys[J]. Journal of Materials Science, 2008, 43(9): 3009-3027. [3] Li J H, Albu M, Hofer F, et al.Solute adsorption and entrapment during eutectic Si growth in Al-Si-based alloys[J]. Acta Materialia, 2015, 83: 187-202. [4] Barrirero J, Li J H, Engstler M, et al.Cluster formation at the Si/liquid interface in Sr and Na modified Al-Si alloys[J]. Scripta Materialia, 2016, 117: 16-19. [5] Li J H, Barrirero J, Engstler M, et al.Nucleation and growth of eutectic Si in Al-Si alloys with Na addition[J]. Metall Mater Trans A-Phys Metall Mater Sci, 2015, 46A(3): 1300-1311. [6] Dahle A K, Nogita K, Zindel J W, et al.Eutectic nucleation and growth in hypoeutectic Al-Si alloys at different strontium levels[J]. Metall Mater Trans A-Phys Metall Mater Sci, 2001, 32(4): 949-960. [7] Haque M M.Effects of strontium on the structure and properties of aluminium-silicon alloys[J].J Mater Process Tech, 1995,55(3,4):193-198. [8] Zhu Z J, Zeng S Y, Jin Y X.Morphologies of strontium-modified A357 alloy and its mechanisms[J]. Transactions of Nonferrous Metals Society of China, 2003, 13(2): 325-328. [9] Liu X R, Zhang Y D, Beausir B, et al.Twin-controlled growth of eutectic Si in unmodified and Sr-modified Al-12.7%Si alloys investigated by SEM/EBSD[J]. Acta Materialia, 2015, 97: 338-347. [10] Timpel M, Wanderka N, Schlesiger R, et al.The role of strontium in modifying aluminium-silicon alloys[J].Acta Materialia,2012,60(9):3920-3928. [11] Mao F, Yan G, Xuan Z, et al.Effect of Eu addition on the microstructures and mechanical properties of A356 aluminum alloys[J]. Journal of Alloys and Compounds, 2015, 650: 896-906. [12] Li J H, Wang X D, Ludwig T H, et al.Modification of eutectic Si in Al-Si alloys with Eu addition[J]. Acta Materialia, 2015, 84(85):153-163. [13] Ludwig T H, Li J, Schaffer P L, et al.Refinement of eutectic Si in high purity Al-5Si alloys with combined Ca and P additions[J]. Metallurgical & Materials Transactions A, 2015, 46(1):362-376. [14] Ludwig T H, Dæhlen E S, Schaffer P L, et al.The effect of Ca and P interaction on the Al-Si eutectic in a hypoeutectic Al-Si alloy[J]. Journal of Alloys & Compounds, 2014, 586(6):180-190. [15] Farahany S, Ourdjini A, Idrsi M A, et al.Evaluation of the effect of Si, Sb, Sr and cooling condition on eutectic phases in an Al-Si-Cu alloy (ADC12) by in situ thermal analysis[J]. Thermochim Acta, 2013, 559:59-68. [16] Li J H, Schumacher P.Effect of Y addition and cooling rate on refinement of eutectic Si in Al-5 wt.%Si alloys[J]. International Journal of Cast Metals Research, 2012, 25(6): 347-357. [17] 接金川. 钇元素对ZL101A合金组织和性能的影响[D]. 哈尔滨:哈尔滨工业大学材料科学与工程学院, 2008. Jie Jin-chuan.Effect of Yttrium element on microstructure and mechanical properties of ZL101A alloy[D]. Harbin:College of Materials Science and Engineering, Harbin Institute of Technology, 2008. [18] Li Z H, Yan H.Modification of primary alpha-Al, eutectic silicon and beta-Al5FeSi phases in as-cast AlSi10Cu3 alloys with (La +Yb) addition[J]. Journal of Rare Earths, 2015, 33(9): 995-1003. [19] 程仁菊, 潘复生, 王维青. Al-Sr中间合金制备及应用的发展现状[J]. 轻合金加工技术, 2006, 34(7):5-11. Chen Ren-ju, Pan Fu-sheng, Wang Wei-qing.Development status of preparation and application of Al-Sr master alloy[J]. Light Alloy Fabrication Technology, 2006, 34(7):5-11. [20] Hamilton D R, Seidensticker R G.Propagation mechanism of germanium dendrites[J]. Journal of Applied Physics, 1960, 31(7):1165-1168. [21] Zhang D L, Cantor B.Heterogeneous nucleation of solidification of Si by solid Al in hypoeutectic Al-Si alloy[J]. Metall Mater Trans A, 1993, 24(5):1195-1204. [22] Lu S Z, Hellawell A.The mechanism of silicon modification in aluminum-silicon alloys: impurity induced twinning[J]. Metall Mater Trans A, 1987, 18(10):1721-1733. [23] Chen Z, Zhang R.Effect of strontium on primary dendrite and eutectic temperature of A357 aluminum alloy[J]. China Foundry, 2010, 7(2):149-152. [24] Mondolfo L F.Aluminum Alloys : Structure and Properties[M]. London: Butterworths, 1976. [25] Yang Ming-bo, Pan Fu-sheng, Cheng Ren-ju, et al.Effects of Al-10Sr master alloys on grain refinement of AZ31 magnesium alloy[J]. Trans Nonferrous Met Soc, 2008,18(1):52-58. [26] Liao Cheng-wei, Chen Jian-chun, Li Yun-long, et al.Modification performance on 4032 Al alloy by using Al-10Sr master alloys manufactured from different processes[J]. Progress in Natural Science: Materials International 2014, 24(2): 87-96. [27] Kubaschewski O, Alcock C B, Spencer P J.Materials Thermochemistry [M]. Oxford: Pergamon Press, 1993. [28] 库尔兹. 凝固原理[M].4版. 李建国,胡侨丹译.北京: 高等教育出版社,2010. |
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