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Journal of Jilin University Science Edition
ISSN 1671-5489
CN 22-1340/O
主 任:韩啸
编 辑:赵立芹 王健 单凝 李琦
电 话:0431-88499428
E-mail:sejuj@jlu.edu.cn
地 址:长春市南湖大路5372号
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Table of Content
26 September 2014, Volume 52 Issue 05
Rings with Strongly Symmetric Endomorphisms and Their Extensions
WANG Yao, XUE Ling, REN Yanli
Journal of Jilin University Science Edition. 2014, 52 (05):  861-868. 
Abstract ( 207 )   PDF (358KB) ( 415 )  

The rings with strongly symmetric endomorphisms were investigated. Let α be an endomorphism of ring R. Ring R is known as strong right α-symmetric if abα(c)=0 implies acb=0 for any a,b,c∈R. The relationships between strong α-symmetric ring and symmetric, strong α-reversible or strong α-semicommutative ring were discussed, and some extensions of strong α-symmetric rings were st
udied. It is proved that 1) Ring R is strong α-symmetric if and only if R is symmetric and α-compatible; 2) Ring R is strong α-symmetric if and only if R[x;α] is strong α-symmetric; 3) If α is an automorphism of right Ore ring R, then R is strong α-symmetric if and only if the classical right quotient ring Q(R) of R is strongα-symmetric.

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A HilbertType Integral Inequality Related to the Riemann Zeta Function
YANG Bicheng, CHEN Qiang
Journal of Jilin University Science Edition. 2014, 52 (05):  869-872. 
Abstract ( 178 )   PDF (285KB) ( 204 )  

Introducing independent parameters, applying the techniques of real analysis and the way of weight functions, the authors presented a new Hilberttype integral inequality with the kernel of cosecant function and a best constant factor related to the Riemann zeta function and deduced the equivalent form and some homogeneous forms for a particular parameter.

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Automorphism Group of Heisenberg JordanLie Algebra
ZHOU Jia
Journal of Jilin University Science Edition. 2014, 52 (05):  873-880. 
Abstract ( 200 )   PDF (338KB) ( 438 )  

We introduced the notion of Heisenberg Jordan-Lie algebra so as to investigate some subgroups of the automorphism group Aut(H) of Heisenberg JordanLie algebra H. Moreover, we discussed some basic structure of the automorphism group Aut(H) in the case of H being lowdimensional.

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A Class of Nonlinear Commuting Maps on Triangular Algebras
YU Weiyan, ZHANG Jianhua
Journal of Jilin University Science Edition. 2014, 52 (05):  881-887. 
Abstract ( 275 )   PDF (326KB) ( 247 )  

The authors studied a class of nonlinear  commuting maps (namely, modulo linear commuting map) on triangular algebras, described the forms of such maps, and gave such a sufficient condition that every modulo linear commuting map on triangular algebras is proper. As an application, it is proved that every modulo linear commuting map on nest algebras is proper.

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Weak Estimates for LittlewoodPaley Operators withRough Kernels on the Weighted Morrey Spaces
DAI Huiping, TAO Shuangping, GOU Yinxia
Journal of Jilin University Science Edition. 2014, 52 (05):  888-894. 
Abstract ( 240 )   PDF (339KB) ( 263 )  

With the help of the weighted inequalities and boundedness on the weighted Lebesgue spaces, the weak type estimates of the square function with rough kernel and LittlewoodPaley g*λfunction are obtained respectively on the weighted Morrey spaces Lp,κ(ω) as the kernel 
Ω∈Lq(Sn-1)(1<q≤∞) is degreezero homogeneous  and has mean value zero on Sn-1.

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The Compact Timelike Submanifolds in the de Sitter Space
HU Youjing, JI Yongqiang
Journal of Jilin University Science Edition. 2014, 52 (05):  895-901. 
Abstract ( 211 )   PDF (330KB) ( 242 )  

Based on  the  moving frams, the Ricci identity and the Laplacian about the squared norm of the second fundamental form for the timelike submanifolds in de Sitter space were calculated, and some necessary conditions for the compact maximal timelike submanifold in de Sitter space were given.

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Solving Systems of Fractional Differential Equations byVariational Iteration Method
DAI Qun, WANG Changjia, LI Huilai
Journal of Jilin University Science Edition. 2014, 52 (05):  901-905. 
Abstract ( 221 )   PDF (293KB) ( 403 )  

The authors described approximate solutions for systems of fractional differential equations by the variational iteration method, and modified the correction function. Numerical results reveal that variational iteration method is very effective and accurate for obtaining approximate solutions of systems of fractional differential equations.

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Polynomial First Integral of Reversible Lotka-Volterra Model in BelousovZhabotinsky Reaction
XING Wei, TIAN Hua
Journal of Jilin University Science Edition. 2014, 52 (05):  906-910. 
Abstract ( 200 )   PDF (305KB) ( 301 )  

We considered the polynomial first integral for reversible Lotka-Volterra model which describes the oscillatory chemical dynamics in a closed isothermal reaction. Making use of integrability theories of semiquasihomogeneous systems, we proved that the LotkaVotterra model is a unique polynomial first integral.

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Error Formulas of Lagrange Projectors for Cartesian Point Sets
LI Zhe, SUN Yan
Journal of Jilin University Science Edition. 2014, 52 (05):  911-915. 
Abstract ( 170 )   PDF (313KB) ( 312 )  

This paper generalized good error formulas and considered Lagrange interpolation for Cartesian point sets. Taking 3dimension Cartesian point sets for example, we provided the integral form of error formulas for this class of interpolation problem using the relationship between the Bspline and  finite difference quotient. The results can be generalized in the ddimensional Cartesian point sets.

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Complete Moment Convergence for Moving Average ProcessesGenerated by Strong Mixing Sequences
HU Zhicai, GUAN Lihong, JIA Xiuli, WANG Zhenhua
Journal of Jilin University Science Edition. 2014, 52 (05):  916-920. 
Abstract ( 129 )   PDF (302KB) ( 221 )  

Let {Yi,-∞<i<∞} be a sequence of identically disributed strong mixing random variables, and {ai,-∞<i<∞} be an absolutely summable sequence of real numbers. By means of the moment inequality of strong mixing sequence and in consideration of the property of slowly varying function, we obtained the complete moment convergence and strong law of large numbers for moving average processes generated by strong mixing sequences under some suitable conditions.

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Precise Asymptotics for Product of Partial Sums of φ-Mixing Sequences
ZOU Guangyu
Journal of Jilin University Science Edition. 2014, 52 (05):  921-926. 
Abstract ( 147 )   PDF (314KB) ( 213 )  

Precise Asymptotics for Product of Partial Sums of φ-Mixing Sequences

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Strong Convergence Results for Weighted Sums of ρ-Mixing Random Variables Sequence
TAN Xili, WANG Miao
Journal of Jilin University Science Edition. 2014, 52 (05):  927-932. 
Abstract ( 162 )   PDF (316KB) ( 304 )  

The authors studied the complete convergence for weighted sums of ρ--mixing random variables sequence without assumption of identical distribution via truncation method for ρ--mixing random variables sequence, Hlder inequality, Markov inequality, Jensen inequality, Cr inequality, moment inequality and Rosenthal inequality. As an example of application, we further extended the MarcinkiewiczZygmund type strong law of large numbers
for weighted sums of ρ--mixing random variables sequence with the aid of Borel-Cantelli lemma.

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Homotopy Method for PMixed Linear Complementarity Problem
XUE Dongmei, JIANG Boyang, WANG Xiuyu
Journal of Jilin University Science Edition. 2014, 52 (05):  933-936. 
Abstract ( 299 )   PDF (295KB) ( 232 )  

A homotopy equation was constructed for the P-mixed linear complementarity problem, the existence, boundedness and convergence of the homotopy path were proved, the solvability of P-mixed linear complementarity problem was obtained. Thus an interiorpoint method of P-mixed linear complementarity problem has been established.

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Global Optimization for Quadratic Bilevel Programming Problem
XU Junyan, GAO Yingying, MIAO Zhuang, LIU Qinghuai
Journal of Jilin University Science Edition. 2014, 52 (05):  937-942. 
Abstract ( 317 )   PDF (342KB) ( 345 )  

A parametric algorithm was proposed for solving the nonisolated global optimal solution of quadratic bilevel programming problem in view of most existing approximate methods for solving these problems sometimes providing an infeasible solution, or a solution far from the ture optimum. The algorithm overcomes these limitations. Numerical results presented show the effectiveness of this method.

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SecondOrder Asymptotic Epiderivative and Application
ZHANG Aihong, XU Yihong, TU Xiangqiu
Journal of Jilin University Science Edition. 2014, 52 (05):  943-948. 
Abstract ( 231 )   PDF (329KB) ( 209 )  

The strict efficiency of setvalued optimization was considered in real normed linear space by a new secondorder asymptotic epiderivative. With the help of secondorder asymptotic tangent cone, a new secondorder asymptotic epiderivative was introduced. At the same time,  an example was given to show that its existence condition is weaker than that of secondorder asymptotic tangent derivative. By applying the derivative and properties of a dilating cone, an optimality necessary condition of locally strictly efficient element for setvalued optimization was established.

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Finite Difference Method for Solving AmericanPut Option under the BlackScholes Model
LI Jingshi, WANG Zhiyu, ZHU Benxi, SONG Haiming
Journal of Jilin University Science Edition. 2014, 52 (05):  949-953. 
Abstract ( 558 )   PDF (566KB) ( 403 )  

This paper deals with the American put option pricing problem governed by the BlackScholes equation. Applying finite difference method coupled with Newton’s method to solve the BlackScholes equation, we can get the numerical approximations of the option price and the optimal exercise boundary simultaneously. Numerical experiments verify the efficiency of the method.

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Spectral Analysis of Normalized Laplacian Matrix in Random Graphs
ZHANG Ling, DING Xue
Journal of Jilin University Science Edition. 2014, 52 (05):  954-960. 
Abstract ( 257 )   PDF (357KB) ( 264 )  

We investigated the convergence of the empirical spectral distribution (ESD) of normalized Laplacian matrix from random graph with given expected degree. It was shown that the ESD of normalized Laplacian matrix converges to a fixed probability distribution when the expected degree satisfys some assumptions, but the fixed probability distribution may be different at different places.

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Hopf Bifurcation Analysis and Bifurcation Controlof a Relative Rotation System
ZHANG Zhonghua, LI Pengsong, FU Jing
Journal of Jilin University Science Edition. 2014, 52 (05):  961-968. 
Abstract ( 207 )   PDF (1781KB) ( 229 )  

Hopf bifurcation type and Hopf bifurcation control of a relative rotation dynamical system with nonlinear damping force were mainly studied. Firstly, the original system was changed to a twodimensional system via center manifold theory, and the stability coefficient of the twodimensional system was calculated to determine the Hopf bifurcation type of the original system. Then, the cubic nonlinear controller based on Washout filter theory was designed to control Hopf bifurcation, and the effects of control parameter on Hopf bifurcation type and periodic solution’s amplitude were discussed. The results show that when the control parameter satisfies certain condition, the potential threat subcritical Hopf bifurcation of original will be changed to supercritical Hopf bifurcation, thus the normal vibration of original system is guaranteed, and the amplitude of vibration will decrease with the reduction of the control parameter.

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Blowup Criterion for a Class of CompressibleNonNewtonian Fluids with Vacuum
LI Huapeng, ZHU Xiuli, LI Pengsong, YUAN Hongjun
Journal of Jilin University Science Edition. 2014, 52 (05):  969-970. 
Abstract ( 200 )   PDF (257KB) ( 242 )  

We obtained a blowup criterion for strong solutions to a class of compressible non-Newtonian fluids just in terms of the derivative of the velocity using the proof of contradiction. In other words, if the derivative of the velocity remains bounded as time t approaches to the critical time, a local strong solution can be continued globally in time. In addition, the initial vacuum states are allowed in our cases.

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Efficient Improvement of Preconditioned ConjugateGradient Method for Structural Static Reanalysis
LIU Haifeng, LI Zhengguang
Journal of Jilin University Science Edition. 2014, 52 (05):  971-974. 
Abstract ( 250 )   PDF (507KB) ( 243 )  

This paper deals with the implementation of preconditioned conjugate gradient method (PCG) for structural static reanalysis. The implementation of PCG is revised by exploring sparsity of incremental stiffness matrices so that the computational cost and time can be reduced. Numerical example is given to show the effectiveness of the method.

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Cellular Automata Simulation for Bubbles Annihilation in a Large Numbers
HU Yajun, YAN Guangwu
Journal of Jilin University Science Edition. 2014, 52 (05):  975-978. 
Abstract ( 195 )   PDF (2758KB) ( 187 )  

With the help of a proposed cellular automata model for the twodimensional bubble annihilation and a honeycomb structure instead of the twodimensional bubbles, we simulated the process of the bubble collapse at a load beyond the critical load. This result shows the process meets Zipf’s law.

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Universal Bases for a Class of TwoDimensional Multiarrangements
GAO Ruimei, PEI Donghe
Journal of Jilin University Science Edition. 2014, 52 (05):  979-981. 
Abstract ( 192 )   PDF (267KB) ( 250 )  

For a set of multiarrangements, we gave the concept of universal basis, offered the definition of (1,2)type multiarrangement of twodimensional, and also constructed the universal bases for all of them.

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Fault Diagnosis of Equipment Based on Fault Tree Combined with Bayesian Network
LIU Shufen, YANG Shuangshuang, WANG Hui
Journal of Jilin University Science Edition. 2014, 52 (05):  982-988. 
Abstract ( 209 )   PDF (552KB) ( 192 )  

A new equipment fault diagnosis method was proposed. In this method, we established the fault diagnosis Bayesian network through the combination of the fault tree with Bayesian network, and used joint tree to reason out the fault diagnosis based on the diagnosis fault Bayesian network. The method can solve the problems that modelling hardly and weakly reasoning ability caused by respectively using fault tree and Bayesian network. Fault diagnosis to a deck lighting system of a ship was carried out, and then the probability distributions of fault nodes were calculated, as a result, the fault of deck lighting system can be located quickly and accurately.

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Design of Central Navigation System Based onCOMPASS/GPS Dual Switch
ZHENG Xiaotian, QIN Guihe, DONG Jinnan, CHEN Hong
Journal of Jilin University Science Edition. 2014, 52 (05):  989-994. 
Abstract ( 184 )   PDF (1535KB) ( 374 )  

The authors proposed a new central navigation system based on switching between COMPASS and global positioning system (GPS). After analyzing
the signal carrier to noise ratio of the two positioning modes, the system achieved dual mode switch and solved signal incontinuous problem in the general
dualmode positioning system. Also the dynamic traffic information has been introduced into the process of routing planning, which helps to solve the problem that traditional vehicle navigation system can not provide flexible routing planning based on realtime traffic condition. This paper formulates simple data transfer protocol between vehicle and server, which simplifies the general protocol between them. Experimental results show that this system can maintain a higher quality of satellite data and has achieved the goal of the dynamic navigation based on traffic situation.

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Database FullText Retrieval Based on Lucene Index
YUE Shaomin, LI Wanlong, WANG Lu, GUANG Shunli
Journal of Jilin University Science Edition. 2014, 52 (05):  995-1000. 
Abstract ( 210 )   PDF (477KB) ( 345 )  

The traditional database retrieval has a lot of problems, such as the slower retrieval speed, the incomplete results, and disorderly retrieval results and so on. This paper designs a database index structure based on the Lucene index structure, the full text retrieval tool and puts forward the concept of record inverted index list. So Website can be retrieved by the keywords in the index library, not following the traditional sequential search way, which greatly improves the retrieval efficiency. At the same time, experimental results show that the database fulltext retrieval basedLucene has the advantages of high recall and the orderly retrieval results.

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Planning of Airborne Patrolling Path for Forest FirePrevention Based on Genetic Algorithms
XIE Yangsheng, HUANG Shuisheng, LI Xingying, TANG Xiaoming
Journal of Jilin University Science Edition. 2014, 52 (05):  1001-1006. 
Abstract ( 180 )   PDF (1214KB) ( 305 )  

A planning method based on genetic algorithms for forest fire airborne patrolling path was proposed after the factors, including landforms, distribution of forest resources, forest fire occurrence regulation, airborne platform’s performance, had been fully taken into account. The results of tested region show that the method can not only make the path shorter than the original path (46.06%) but also meet the requirements of covering the monitoring area.

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L3/2 Regularized Graph Nonnegative Matrix Factorization
DU Shiqiang, SHI Yuqing, MA Ming, WANG Weilan
Journal of Jilin University Science Edition. 2014, 52 (05):  1007-1013. 
Abstract ( 266 )   PDF (3275KB) ( 471 )  

This paper presents a novel algorithm called L3/2 regularized graph nonnegative matrix factorization, which was based on the convex and smooth L3/2 norm. When original data is factorized in lower dimensional space by nonnegative matrix factorization, L3/2 regularized graph nonnegative matrix factorization preserves the local structure and intrinsic geometry of data, with the aid of  the convex and smooth L3/2 norm as sparse constrain for the low dimensional feature. An efficient multiplicative updating procedure was produced along with its theoretic justification of the algorithm convergence. Compared with nonnegative matrix factorization and its improved algorithms based on sparse representation, the proposed method achieves better clustering results, which is shown by experiment results on ORL face database, USPS handwrite database, and COIL20 image database.

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Influence of Actual Transmission Distance on Quantum Key Distribution System
WU Jianan, WEI Rongkai, HAN Jiawei,WANG Shigang, LIU Guixia, SONG Lijun
Journal of Jilin University Science Edition. 2014, 52 (05):  1014-1017. 
Abstract ( 170 )   PDF (447KB) ( 396 )  

A long distance peer to peer quantum key distribution experimental system of polarization encoding was built based on BB84 protocol. With the help
of this experimental platform, quantum key distribution experiment with 5,10,15 km three different transmission distances was completed and the main parameters of the system  was collected in real time for data analysis. The experimental results show that with the increase of quantum fiber channel distance from sending end to receiving end, the system bit generation rate and the amount of key generated by the system would drop, the bit error rate of signal state and decoy state would increase within statistical time. The experimental results have theoretical and practical value for practical development of the longrange security quantum key distribution system.

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Automatic and Safe Protection Method of User Cookie
XIONG Dayuan, WANG Huize, LIU Chengsheng, YANG Changyuan
Journal of Jilin University Science Edition. 2014, 52 (05):  1018-1021. 
Abstract ( 214 )   PDF (361KB) ( 325 )  

To solve the safety issues, we proposed a new way of automatic safety protection for user cookies. The cookie was stored in encrypted removable storage devices, and then the fingerprint identification recognition was carried out. This enables the program full background operation: cookie automatic move, transfer, storage and deletion. In this process, users were allowed to conveniently perform network login on different computers in the same cookie application environment. This new method can effectively protect the privacy, and create more convenience for users.

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Design of SPI Interface Flash Controller Based on FPGA
ZHAO Qingping, LI Suwen, DU Weining, JIANG Enhua
Journal of Jilin University Science Edition. 2014, 52 (05):  1022-1026. 
Abstract ( 454 )   PDF (1982KB) ( 484 )  

The authors presented a designed method using serial peripheral interface controller based on field programmable gate array. Using logic resources of FPGA with the ability to produce accurate time series, we can expediently readwrite and wipe SPI flash and store data rapidly and accurately. It also expounds the designing process of SPI controller, which utilizes the simulation and verification by Modelsim and uses VHDL hardware description lang
uage to programme. Then we downloaded the program to FPGA development board to test and verify the readwrite and wipe SPI flash and finally operated the SPI interface flash. It is proved that the method is correct and reliable, and has general applicability to the system designment of the flash controller. This method with FPGA as the control core of system achieved data storage for a long time.

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Detection of the Coating/Substrate Bonding Properties with Laser Excitation and Interferometer Test
SUN Jian, JIN Wei, HAN Qingbang
Journal of Jilin University Science Edition. 2014, 52 (05):  1027-1030. 
Abstract ( 182 )   PDF (916KB) ( 214 )  

The pulse laser was used to produce laser beam that directly irradiates on the interface between the epoxy coat and aluminum substrate to excite the acoustic waves, an optical interferometer was applied to detecting displacement on the rear epicenter of the aluminum substrate. The results of this experiment show that the amplitude ratio of direct wave and reflected wave is directly related with the interfacial bonding characteristics. The described method could be used to evaluate bonding quality for similar structure.

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Reaction Properties of SiGe FilmCodeposition Process in Ionic Liquid
YU Zhaoliang, LI Zhongyue, LI Weiyan, LI Ji, MENG Xiangdong, LI Haibo
Journal of Jilin University Science Edition. 2014, 52 (05):  1031-1034. 
Abstract ( 138 )   PDF (1463KB) ( 225 )  

A SiGe film was electrodeposited in [EMIm]Tf2N ionic liquid. In order to study the reaction process of SiGe on electrode surface, cyclic voltammetry curves at different scan rates were determined. The microstructure and composition of the SiGe film were characterized by scanning electron microscopy and energy dispersive spectroscopy. An irreversible process of the codeposition of SiGe was controlled by diffusion in [EMIm]Tf2N ionic liquid. The
 cathodal transfer coefficient (α=0.175) and diffusion coefficient (D0=6.64×10-7 m/s) of an electrode reaction process of SiGe codeposition were calculated based on the cyclic voltmmetric curve.

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Design and Realization of  Novel DiamondShapedUltrawideband Antenna
CAO Xi, TIAN Xiaojian
Journal of Jilin University Science Edition. 2014, 52 (05):  1035-1038. 
Abstract ( 222 )   PDF (1416KB) ( 277 )  

A novel ultra\|wideband antenna with diamondshaped patch was designed and fed by a coplanar waveguide. The size of the substrate is 26 mm×24 mm×0.8 mm and the substrate material uses FR4 with a relative permitivity of 4.4. The patch was  optimized twice by  ground plant’s first order optimization. The simulated and experimental results demonstrate that the bandwidth (VSWR≤2) starts from 2.0 GHz up to 14.5 GHz and  relative bandwidth comes to  151%. This diamondshaped UWB antenna has the advantages of simple structure and miniaturization that can be applied to various UWB systems.

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Fracture of Cu Nanowire upon Stretch by AtomicScale Molecular Dynamic Simulation
CHEN Nianke, LI Xianbin
Journal of Jilin University Science Edition. 2014, 52 (05):  1039-1043. 
Abstract ( 242 )   PDF (7405KB) ( 280 )  

To explore the fracture mechanism of metal nanowires,  a fracture process of Cu nanowire upon stretch was theoretically studied by molecular dynamic (MD) simulations based on embeddedatom method (EAM) potential. The relationship between stress, strain and dislocation before fracture as well as the morp
hology evolution after fracture was analyzed. The results demonstrate that the tips on the two ends of the nanowire can stuck the dislocation motion. Then the stacking fault by the first partial dislocation could be annihilated by a full dislocation formed by another partial dislocation. This process  can thus enhance the fracture strength. The sharp structure after fracture can retract and become obtuse spontaneously. The atomic scale analysis of the morphology change demonstrates that the fracture is a process of eliminating the high energy structures, such as isolated atoms, twin boundary and surface kink. The surface of the fracture finally emerge many (111) facets with lower energies. Therefore the physical mechanism is attributed to the rule of energy minimization.

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Solar Cell Based on Benzotrithiophene Copolymerand Fullerene Derivative
YIN Li, YANG Dalei, WANG Zhongliang, JIANG Xin
Journal of Jilin University Science Edition. 2014, 52 (05):  1044-1048. 
Abstract ( 183 )   PDF (3890KB) ( 408 )  

The energy level of the electron acceptor plays an important role in bulk heterojunction solar cells. A conjugated polymer BTT-BTz  as electron donor and fullerene derivatives PC70BM, PC60BM and IC60BA as acceptor with different energy levels was studied, and the influence of the acceptor energy level on the opencircuit voltage (Voc) , shortcircuit current density (Jsc), fill factor (FF) and power conversion efficiency (PCE) were investigated. The BTTBTz/IC60BA based device exhibited a high Voc of 1.06 V, but the poor PCE of 1.49% due to the lower Jsc. Although the Voc of the devices based on BTTBTz/PC60BM and BTTBTz/PC70BM is decreased, they displayed promising efficiencies of 322% and 5.06%.

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A Multiscale Computer Simulation of the Solvation Behavior of nAlkane in Supercritical Carbon Dioxide
YANG Siyu, JIAO Guisheng, LV Wenfeng, YANG Yongzhi, QIAN Hujun, JIA Chuyuan, TANG Jun
Journal of Jilin University Science Edition. 2014, 52 (05):  1049-1054. 
Abstract ( 261 )   PDF (1889KB) ( 369 )  

The solvation behavior of n-alkane in supercritical CO2 was studied via the multiscale computer simulations combining atomistic molecular dynamics (MD) and dissipative particle dynamics (DPD) techniques. Firstly, the physical properties such as density, solubility parameter were calculated from atomistic molecular dynamics simulations. Next, a dissipative particle dynamics model was constructed with the solubility parameters to simulate the solvation behavior of n-C39 in supercritical CO2. The solubility of n-C39 in supercritical CO2 at different pressures was measured by visual images and order parameters. The minimum miscible pressure of n-C39 in supercritical CO2 was also estimated based on the order parameter values at different pressures.

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Hydrothermal Synthesis and Luminescent Properties ofNon RareEarth Mn Doped SrGe4O9 Red Phosphor
LI Shan, YE Tiannan, LU Yang, WEI Xiao
Journal of Jilin University Science Edition. 2014, 52 (05):  1055-1058. 
Abstract ( 5897 )   PDF (2291KB) ( 358 )  

A hydrothermal method was used to synthesize Mn4+ doped SrGe4O9 red phosphor. The crystal structure and luminescent properties of the SrGe4O9∶Mn4+ were characterized by XRD and FS. The SrGe4O9∶Mn4+ phosphor emits red emission at 656 nm due to the 2E24A2transition of Mn4+. The valence state of Mn was demonstrated by EPR. In addition, the influence of Mn4+ doping concentration on the luminescent properties of the phosphor was studied and the luminescent properties of the hydrothermally prepared SrGe4O9∶Mn4+ phosphor was compared with those of the control sample prepared from solid state reaction.

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Molecular Imprinted Interaction between Salbutamol andEach of Different Functional Monomers
SHI Yang, LIU Junbo, TANG Shanshan, JIN Ruifa
Journal of Jilin University Science Edition. 2014, 52 (05):  1059-1066. 
Abstract ( 272 )   PDF (1449KB) ( 302 )  

SAL was taken as a template, methacrylic acid (MAA), acrylamide (AM), and 4-vinyl pyridine (4-VP) were taken as single functional monomers, MAA and AM were taken as hybrid functional monomers. Density functional theory (DFT) at the LCWPBE level was used to investigate the geometry configuration optimization, the action sites, the natural bond orbital (NBO) charges, the binding energies of the imprinted molecule, and the solvation energy. The mechanisms between salbutamol and each of different functional monomers were discussed. The results show that SAL interacted with the functional monomers by hydrogen bonds, and they were matchable in steric structure and chemical groups, resulting in ordered compounds. The interaction between SAL and MAA is the strongest. The polymer with a ratio of SALMAA (1∶4) in acetonitrile (ACN) had the lowest binding energy and the maximum charge transfer trend. Under the guidance of calculation results, the SALMIPs were synthesized by the precipitation polymerization. The results indicate that when the ratio of SALMAA is 1∶4, the SALMIPs have the maximum adsorption capacity, and the conclusion of experiment is consistent with the results of calculation.

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Synthesis, Structure and Photovoltaic Property of M-1,3,5-benzenetricarboxylato Coordination Polymers (M=Cu and Co)
DONG Jiaojiao, JIN Jing, YAN Xin, QU Xiujuan, NIU Shuyun
Journal of Jilin University Science Edition. 2014, 52 (05):  1067-1072. 
Abstract ( 424 )   PDF (1115KB) ( 273 )  

Two 1,3,5benzenetricarboxylato coordination polymers {[Cu2(Hbtc)2(H2O)6]·ppz·H2O}n(1) and {[Co2(btc)2(H2O)6]·(H2ppz)·(H2O)}n(2), (H3btc=1,3,5benzenetricarboxylic acid, ppz=piperazine) have been hydrothermally synthesized and characterized by IR, UV-Vis-NIR,  elemental analysis and X-ray single crystal diffraction. Structural analysis reveals that the two coordination polymers both crystallize in the triclinic system with P-1 space group and both possess the M1btcM2btcM1polymeric zigzagchain structure, but the coordination geometry around metal ions is different and the same organic molecules exhibit different forms. The photovoltaic property was investigated by surface photovoltage spectroscopy (SPS). The results reveal that the two polymers all exhibit surface photovoltage responses under UVVis lightinducement in SPS, and the coordination environment of the metallic ion affect the response scope. The SPS responses were analyzed and assigned by the combination of the energy band theory of semiconductor and crystal field theory.

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Synthesis of a Novel Chemically Amplified Resist for i-Line Lithography
XU Na, MENG Lei
Journal of Jilin University Science Edition. 2014, 52 (05):  1073-1076. 
Abstract ( 309 )   PDF (1094KB) ( 350 )  

An ester acetal polymer with high acidolysis activity was combined with diazonaphthoquinone sulfonate to form a novel photoresist, which can be used as a chemically amplified iline (365 nm) photoresist with a high sensitivity. Under the action of acid, the polymer can be decomposed into small molecular fragments. Compared with the traditional photoresist system, it performs dissolution rate higher when developed with diluted alkali, and can further improve the sensitivity. And the image with linewidth less than 0.5 μm can be made.

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Reaction Kinetics of CoFeMg Oxide Nano ParticlesFentonDegraded Methylene Blue
LIN Songzhu, LI Tingting, JIA Ruokun
Journal of Jilin University Science Edition. 2014, 52 (05):  1077-1083. 
Abstract ( 182 )   PDF (3186KB) ( 355 )  

CoFeMg oxide nanocrystals were prepared with solgel method and characterized as a catalyst. SEM and XRD were used to characterize the catalyst, methylene blue was used to study the synergistic degradation of the catalyst and H2O2, the dynamic process of oxidative degradation of methylene
blue was studied by the steadystate approximation method. Results show that CoFeMg Fenton reaction system composed of CoFeMg oxide nanocrystals used as a heterogeneous Fentonlike catalyst and H2O2 effectively degraded methylene blue. At pH≈7.15, a mass concentration of CoFeMg oxide nanocrystals of 0.8 g/L and concentration of H2O2 of 2 mmol/L, the degradation rate of methylene blue was evaluated to be 95%. Compared with that of traditional Fenton reaction system, the amount of leaching of iron was decreased to 0.2 mg/L under similar conditions. The dynamics results show that Fenton reaction system shows a hydroxyl radicals (·OH) oxidation degradation process of methylene blue, and the reaction was considered as secondary dynamics.

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Synthesis of Comb Amphiphilic Poly(itaconic acid) and  Drug Delivery System with Encapsulated Doxorubicin
ZHANG Xiaonan, YANG Bohan, ZHAO Wai’ou, WANG Jingyuan
Journal of Jilin University Science Edition. 2014, 52 (05):  1084-1090. 
Abstract ( 178 )   PDF (1395KB) ( 297 )  

Poly(itaconic acid) was successfully synthesized by radical polymerization. Afterwards, combshape amphiphilic copolymers PIA-g-DDA were obtained via grafting docecylamine onto the backbone of PIA through amination reaction. Hydrodynamic diameter of the micelle formed by PIA-g-DDA in water was recorded by dynamic light scattering (DLS). The effect of graft density of alkyl on the size of the micelle was investigated, with the results indicating that an increase in the graft level of DDA leads to a decrease in the size of the micelle conversely. Critical micelle concentration (CMC) of the micelle was determined through fluorescence spectrophotometry with pyrene as probe to be 2.01×10-2mg/mL. In the end, the copolymers were employed to encapsulate DOX (DOXorubicin) as a model, namely, drug delivery system PIA-g-DDA@DOX, to demonstrate an ideal encapsulation efficiency and drug loading value, and more importantly sustained release of drugs.

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Synthesis of Comb HPEG/PMA and HPEG/PAA via ATRP
ZHAO Li, REN Dianfu, TIAN Weixing, WANG Hong, CHEN Zhong, HAN Zhaorang
Journal of Jilin University Science Edition. 2014, 52 (05):  1091-1094. 
Abstract ( 274 )   PDF (420KB) ( 377 )  

Comb methyl allyl polyethenoxy etherpolymethyl acrylate (HPEG/PMA) was synthesized with atom transfer radical polymerization (ATRP). FT-IR and 1H NMR were used to identify the structure of HPEG/PMA. The results show that we successfully synthesized  comblike HPEG/PMA. Gel permeation
chromatography (GPC) was used to characterize the molecular weight and molecular weight distribution. The molecular weight was 7.7×103 and molecular weight distribution was 1.11. It indicates that the synthesis of HPEG/PAA with ATRP has good controllability. The HPEG/PMA was hydrolyzed with NaOH 
V(ethanol)∶V(H2O)=1 solution to get HPEG/PAA.

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Determination of New Compound 24(R)-Majoroside R1 in Panax japonicus C.A.Mey.var.Major(Burk.[KG-*3]) C.Y.Wu et K.M.Feng by H
PLCELSD
WANG Jiafu, PENG Shao, LI Lanjie, YANG Jie, SUN Ting, LI Xuwen, JI Yongri, SHI Xiaolei
Journal of Jilin University Science Edition. 2014, 52 (05):  1095-1099. 
Abstract ( 168 )   PDF (439KB) ( 234 )  

The determination of the new compound of 24(R)majoroside R1 in Panax japonicus C.A. Mey. var. Major (Burk.[KG-*3]) C.Y. Wu et
K. M. Feng was developed by HPLC\|ELSD method. The conditions of chromatography were Aglient Zorbax SBC18 Column (ODS, 4.6 mm×250 mm, 5 μm) was adopted; mobile phase was composed of V(methanol)∶V(water)=58∶42; flow rate was set at 1.0 mL/min; temperature of column was set at 25 ℃; carrier gas pressure was set at 1.94×105 Pa tube temperature of ELSD was set at 85 ℃; impactor was set in closed state. As the results show in the range of 0.4—20.0 μg, the linearity of 24(R)majoroside R1 is good, r=0.999 3(n=6), the average recovery was 98.7%, and RSD=1.28% (n=6).

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Binding Pose of the Autotoxin (ATX) Inhibitors Predictedand Molecular Docking with rPAI-1
ZHAN Dongling, ZHENG Mingzhu, HAN Weiwei, LIU Jingsheng
Journal of Jilin University Science Edition. 2014, 52 (05):  1100-1104. 
Abstract ( 273 )   PDF (2092KB) ( 285 )  

The composite fingerprint virtual screening was used to predicate the binding mode of autotoxin’s (ATX) inhibitor. Our results indicate that Thr209,Asp172,Tyr306,Phe210,Leu243,Leu213, and Phe274 are important residues for binding 24 inhibitors (10 lipid and lipidbased inhibitors and 14
small molecule inhibitors). We also predicted the binding mode of plasminogen activator inhibitor 1 (rPAI-1) to ATX. Under the guidance of GRAMM software, the homology modeling of macromolecule inhibitor rPAI1 showed it was docked to ATX. Through molecular dynamics simulation, we predicted the important residues Glu155 and Ala158 involved in the binding of macromolecule inhibitor rPAI-1.

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